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Copernican Letters

High performance membrane materials for gas separation
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High performance membrane materials for gas separation

Authors

  • Aleksandra Wolińska-Grabczyk Centre of Polymer and Carbon Materials, Polish Academy of Sciences, M. Curie-Skłodowskiej 34, 41-819 Zabrze
  • Andrzej Jankowski Centre of Polymer and Carbon Materials, Polish Academy of Sciences, M. Curie-Skłodowskiej 34, 41-819 Zabrze

DOI:

https://doi.org/10.12775/CL.2015.002

Keywords

Polymeric membranes, Inorganic membranes, Mixed matrix membranes, Gas separation

Abstract

The use of membranes in various gas separations has increased significantly in recent times. This review presents some of the recent noteworthy advances in the field of membranes materials for these applications. A description of the most promising groups of high free volume polymers, including polyimides, thermally rearranged (TR) polymers, substituted polyacetylenes, perfluoropolymers, and polymers with intrinsic microporosity (PIM) is provided. High performance, rubbery, polyethers and polyether based copolymers are shown as another important class of polymer membrane materials.  The development of inorganic membranes, which are not bound to the trade-off limitations between permeability and selectivity exhibited by polymers is also presented. The attention is focused on zeolitic materials, metal organic frameworks (MOF), and carbon molecular sieves (CMS). The field of mixed matrix membranes composed of inorganic particles embedded in a polymer matrix is also briefly outlined.

References

. Robeson L.M., Correlation of separation factor versus permeability for polymeric membranes, J. Membrane Sci. 62 (1991) 165-185.

. Yamploskii Y., Polymeric gas separation membranes, Macromolecules, 45 (2012) 3298-3311.

Sanders D.F., Smith Z.P. Guo R., Robeson L.M., McGrath J.E., Paul D.R., Freeman B.D., Energy-efficient polymeric gas separation membranes for a sustainable future: A review, Polymer, 54 (2013) 4729-4761.

. Lau C.H., Li P., Li F., Chung T-S., Paul D.R., Reverse-selective polymeric membranes for gas separations, Prog. Polym.Sci.38, (2013) 740-766.

. Gascon J, Kapteijn F., Zornoza B., Sebastian V., Casado C., Coronas J., Practical Approach to Zeolitic Membranes and Coatings: State of the Art, Opportunities, Barriers, and Future Perspectives, Chem. Mater., 24, (2012) 2829-2844.

Copernican Letters

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Published

2015-12-01

How to Cite

1.
WOLIŃSKA-GRABCZYK, Aleksandra and JANKOWSKI, Andrzej. High performance membrane materials for gas separation. Copernican Letters. Online. 1 December 2015. Vol. 6, pp. 11-16. [Accessed 8 July 2025]. DOI 10.12775/CL.2015.002.
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Issue

Vol. 6 (2015)

Section

CHAPTER 1 – CHEMISTRY

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