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Copernican Letters

Catalytic oxidation of glucose on gold nanoparticles in neutral pH
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Catalytic oxidation of glucose on gold nanoparticles in neutral pH

Authors

  • Magdalena Blicharska Warsaw University, ul. Pasteura 1, 02-093 Warszawa
  • Anna Dobrzeniecka Warsaw University, ul. Pasteura 1, 02-093 Warszawa
  • Sylwia Żołądek Warsaw University, ul. Pasteura 1, 02-093 Warszawa
  • Jadwiga Stroka Warsaw University, ul. Pasteura 1, 02-093 Warszawa
  • Paweł Kulesza Warsaw University, ul. Pasteura 1, 02-093 Warszawa

DOI:

https://doi.org/10.12775/CL.2013.006

Keywords

Inorganic and analytical chemistry / electrochemistry / electrocatalysis.

Abstract

We have demonstrated the importance of stabilizing on the catalytic activity towards glucose oxidation of gold nanoparticles which is dependent on the active metal surface. For this purpose we prepare gold nanoparticles stabilized with oleyl amine (AuNPs-OLA) and compare them with phosphomolybdate-capped gold nanoparticles (AuNPs-PMo12). The electrochemical oxidation of glucose on glassy carbon electrode modified with these gold nanoparticles has been studied in  phosphate buffer (pH=7.4) on glassy carbon electrodes. Under these conditions AuNPs-PMo12 are more active in catalytic process than AuNPs-OLA. This is caused by poorly conductive nature of oleyl amine where the amine molecules stabilize the particles nearly covalently and they form densely packed shell on surface of gold nanoparticles blocking metal active sites. The gold nanoparticles will be also subjected to physical characterization, like Spectrophotometry UV-VIS and Transmission Electron Microscopy (TEM) to verify their structure and morphology. 

References

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Copernican Letters

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Published

2013-12-01

How to Cite

1.
BLICHARSKA, Magdalena, DOBRZENIECKA, Anna, ŻOŁĄDEK, Sylwia, STROKA, Jadwiga and KULESZA, Paweł. Catalytic oxidation of glucose on gold nanoparticles in neutral pH. Copernican Letters. Online. 1 December 2013. Vol. 4, pp. 51-58. [Accessed 5 July 2025]. DOI 10.12775/CL.2013.006.
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Vol. 4 (2013)

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CHAPTER 1 – CHEMISTRY

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