Hydrotalcite-like materials containing manganese – a short review
DOI:
https://doi.org/10.12775/CL.2013.007Abstract
Numerous hydrotalcite-like or their derivatives have been reported as catalysts for a wide variety of chemical processes including selective reduction of nitrogen oxides with ammonia (SCR, DeNOx) or NOx storage/reduction process, selective ammonia oxidation to nitrogen and water vapour (SCO), N2O decomposition (DeN2O) and total oxidation for volatile organic compounds (VOCs). Among them manganese-containing hydrotalcite-like materials and their derivatives seems to possess high activity. This paper gives an overview of Mn-containing catalysts, including the catalyst development and their possible applications. The use of mixed metal oxides obtained from synthetic hydrotalcite-like materials mainly in the role of catalysts for the total VOCs decomposition has been reviewed. Achieved results clearly show that tested materials are candidates for potential application in real catalytic processes.
References
F. Cavani, F. Trifiro, A. Vaccari, “Hydrotalcite-type anionic clays: Preparation, properties and applications.”, Catalysis Today 11 (1991) 173-301.
A. Vaccari, “Preparation and catalytic properties of cationic and anionic clays.”, Catalysis Today 41 (1998) 53-71.
S. Kannan, C.S. Swamy, “Effect of trivalent cation on the physicochemical properties of cobalt containing anionic clays.”, Journal of Materials Science 32 (1997) 1623-1630.
J.S. Valente, M. Sànchez-Cantú, E. Lima, F. Figueras, “Method for large-scale production of multimetallic layered double hydroxides: formation mechanism discernment.”, Chemistry of Maters 21 (2009) 5809-5818.
F. Millange, R.I. Walton, D. O’Hare, “Time-resolved in situ X-ray diffraction study of the liquid-phase reconstruction of Mg–Al–carbonate hydrotalcite-like compounds.”, Journal of Material Chemistry 10 (2000) 1713-1720.
K.-H. Goh, T.-T. Lim, Z. Dong, “Application of layered double hydroxides for removal of oxyanions: A review.”, Water Research 42 (2008) 1343-1368.
F. Kovanda, T. Rojka, J. Dobešová, V. Machovič, P. Bezdička, L. Obalová, K. Jirátová, T. Grygar, “Mixed oxides obtained from Co and Mn containing layered double hydroxides: Preparation, characterization, and catalytic properties.”, Journal of Solid State Chemistry 179 (2006) 812-823.
B.F. Sels, D.E. de Vos, P.A. Jacobs, “Hydrotalcite-like anionic clays in catalytic organic reactions.”, Cataysis Reviews 43 (2001) 443-488.
S. Velu, N. Shah, T.M. Jyothi, S. Sivasanker, “Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg–Al layered double hydroxides.”, Microporous and Mesoporous Materials 33 (1999) 61-75.
F. Malherbe, C. Forano, J.P. Besse, “First coprecipitation of an LDH containing manganese as the divalent cation.”, Journal of Materials Science Letters 18 (1999) 1217-1219.
G.Y. Chao, R.A. Gault, “Quintinite-2H, quintinite-3T, charmarite-2H, charmarite-3T and caresite-3T, a new group of carbonate minerals related to the hydrotalcite-manasseite group.”, The Canadian Mineralogist 35 (1997) 1541-1549.
A. Aisawa, H. Hirahara, H. Uchiyama, S. Takahashi, E. Narita, “Synthesis and thermal decomposition of Mn–Al layered double hydroxides.”, Journal of Solid State Chemistry 167 (2002) 152-159.
P.J. Dunn, D.R. Peacor, T.D. Palmer, “Desautelsite, a new mineral of the pyroaurite group.”, American Mineralogist 64 (1979) 127-130.
H.C.B. Hansen, R.M. Taylor, “Formation of synthetic analogues of double metal-hydroxy carbonate minerals under controlled pH conditions: II. The synthesis of desautelsite.”, Clay Minerals 26 (1991) 507-525.
C. Barriga, J.M. Fernandez, M.A. Ulibarri, F.M. Labajos, V. Rives, ”Synthesis and characterization of new hydrotalcite-like compounds containing Ni(II) and Mn(III) in the hydroxide layers and of their calcination products.”, Journal of Solid State Chemistry 124 (1996) 205-213.
J.W. Murray, L.S. Balistrieri, B. Poul, “The oxidation state of manganese in marine sediments and ferromanganese nodules.”, Geochimica et Cosmochimica Acta 48 (1984) 1237-1247.
J.M. Fernandez, C. Barriga, M.A. Ulibarri, F.M. Labajos, V. Rives, “Preparation and thermal stability of manganese-containing hydrotalcite, [Mg0.75MnII0.04MnIII0.21(OH)2](CO3)0.11•nH2O.”, Journal of Materials Chemistry 4 (1994) 1117-1121.
S. Velu, C.S. Swamy, “Synthesis and physicochemical properties of a new copper-manganese-aluminium ternary hydrotalcite-like compound.”, Journal of Materials Science Letters 15 (1996) 1647-1677.
J.-F. Lamonier, A.-B.Boutoundou, C. Gennequin, M. J. Pérez-Zurita, S. Siffert, A. Aboukais, “Catalytic removal of toluene in air over Co–Mn–Al nano-oxides synthesized by hydrotalcite route.”, Catalysis Letters 118 (2007) 165-172.
F. Kovanda, T. Grygar, V. Dorničák, “Thermal behaviour of Ni-Mn layered double hydroxide and characterization of formed oxides.”, Solid State Sciences 5 (2003) 1019-1026.
F. Kovanda, T. Grygar, V. Dorničák, T. Rojka, P. Bezdičká, K. Jirátová, “Thermal behaviour of Cu-Mg-Mn and Ni-Mg-Mn layered double hydroxides and characterization of formed oxides.”, Applied Clay Science 28 (2005) 121-136.
S. Jouanneau, J.R. Dahn, “Preparation, structure, and thermal stability of new NixCo1-2xMnx(OH)2 (0 ≤ x ≤1/2) phases.”, Chemistry of Materials 15 (2003) 495-499.
M.Y. Lee, Y.J. Kang, S.T. Myung, Y.K. Sun, “Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation.”, Electrochimica Acta 50 (2004) 939-948.
N.V. Kosova, E.T. Devyatkina, V.V. Kaichev, “Mixed layered Ni–Mn–Co hydroxides: Crystal structure, electronic state of ions, and thermal decomposition.”, Journal of Power Sources 174 (2007) 735-740.
M. Zimowska, A. Michalik-Zym, R. Janik, T. Machej, J. Gurgul, R.P. Socha, J. Podobiński, E.M. Serwicka, „Catalytic combustion of toluene over mixed Cu–Mn oxides.”, Catalysis Today 119 (2007) 321-326.
D.A. Aguilera, A. Perez, R. Molina, S. Moreno, “Cu–Mn and Co–Mn catalysts synthesized from hydrotalcites and their use in the oxidation of VOCs.”, Applied Catalysis B 104 (2011) 144-150.
K. Jirátová, P. Čuba, F. Kovanda, L. Hilaire, V. Pitchon, “Preparation and characterisation of activated Ni (Mn)/Mg/Al hydrotalcites for combustion catalysis.”, Catalysis Today 76 (2002) 43-53.
K. Jirátová, J. Mikulová, J. Klempa, T. Grygar, Z. Basal, F. Kovanda, “Modification of Co–Mn–Al mixed oxide with potassium and its effect on deep oxidation of VOC.”, Applied Catalysis B 361 (2009) 106-116.
J. Cheng, J. Yu, X. Wang, L. Li, J. Li, Z. Hao, “Novel CH4 combustion catalysts derived from Cu−Co/X−Al (X = Fe, Mn, La, Ce) hydrotalcite-like compounds.”, Energy & Fuels 22 (2008) 2131-2137.
F. Kovanda, K. Jirátová, “Supported mixed oxide catalysts for the total oxidation of volatile organic compounds.”, Catalysis Today 176 (2011) 110-115.
F. Kovanda, K. Jirátová, “Supported layered double hydroxide-related mixed oxides and their application in the total oxidation of volatile organic compounds.”, Applied Clay Science 53 (2011) 305-316.
J. Ludvíková, F. Kovanda, K. Jirátová, “Mixed oxides of transition metals as catalysts for total ethanol oxidation.”, Chemical Papers 66 (2012) 589-597.
L. Obalová, K. Jirátová, F. Kovanda, K. Pacultová, Z. Lacný, Z. Mikulová, “Catalytic decomposition of nitrous oxide over catalysts prepared from Co/Mg-Mn/Al hydrotalcite-like compounds.”, Applied Catalysis B 60 (2005) 289-297.
L. Obalová, K. Karásková, K. Jirátová, F. Kovanda, ”Effect of potassium in calcined Co–Mn–Al layered double hydroxide on the catalytic decomposition of N2O.”, Applied Catalysis B 90 (2009) 132-140.
L.A. Palacio, J. Velásquez, A. Echavarría, A. Faro, ”Total oxidation of toluene over calcined trimetallic hydrotalcites type catalysts.”, Journal of Hazardous Materials 177 (2010) 407-413.
Z. Mikulová, P. Cuba, J. Balanová, T. Rojka, F. Kovanda, K. Jiratová, “Calcined Ni—Al layered double hydroxide as a catalyst for total oxidation of volatile organic compounds: Effect of precursor crystallinity.”, Chemical Papers 61 (2007) 103-109.
F. Kovanda, K. Jiratová, J. Rymes, D. Kolousek, “Characterization of activated Cu/Mg/Al hydrotalcites and their catalytic activity in toluene combustion.”, Applied Clay Science 18 (2001) 71-80.
V.R. Choudhary, D.K. Dumbre, B.S. Uphade, V.S. Narkhede, “Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides.”, Journal of Molecular Catalysis A 215 (2004) 129-135.
D. Kishore, S. Kannan, “Catalytic isomerization of estragole to anethole over hydrotalcites and HT-like compounds.”, Journal of Molecular Catalysis A 244 (2006) 83-92.
R.S. Jayashree, P. Vishnu Kamath, “Layered double hydroxides of Ni with Cr and Mn as candidate electrode materials for alkaline secondary cells.”, Journal of Power Sources 107 (2002) 120-124.
L. Demourgues-Guerlou, C. Denage, C. Delmas, “New manganese-substituted nickel hydroxides: Part 1. Crystal chemistry and physical characterization.”, Journal of Power Sources 52 (1994) 269-274.
L. Demourgues-Guerlou, C. Denage, C. Delmas, “New manganese-substituted nickel hydroxides: Part 2. Interstratification process upon ageing.”, Journal of Power Sources 52 (1994) 275-281.
L. Demourgues-Guerlou, C. Denage, C. Delmas, “Electrochemical behavior of the manganese‐substituted nickel hydroxides.”, Journal of The Electrochemical Society 143 (1996) 561-566.
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